准噶尔盆地西北缘车排子凸起原油类型与油源     

刘得光  倪云燕  陈建平  李二庭  姚立邈  张枝焕  王绪龙  戴金星 《地质学报》2023,97(5):1576-1597

准噶尔盆地西北缘南部红车断裂带- 车排子凸起油气藏众多,原油物理化学性质和地球化学特征十分复杂,原油类型及其来源长期存在很大争议。本文在准噶尔盆地不同时代烃源岩生成原油典型地球化学特征与主要油源判识指标归纳总结的基础上,对红车断裂带- 车排子凸起原油地球化学特征和来源进行系统分析研究,将该区域原油分为五类,其中三类原油分别来源于二叠系湖相烃源岩、中—下侏罗统煤系烃源岩、古近系安集海河组湖相烃源岩,另外两类为混合原油,分别为来源于二叠系湖相烃源岩的生物降解稠油与中—下侏罗统煤系烃源岩生成的正常原油和古近系湖相烃源岩生成的正常原油的混合原油。红车断裂带石炭系—白垩系油藏原油主要来源于沙湾凹陷二叠系湖相烃源岩,车排子凸起东北部春风油田稠油来源于沙湾凹陷二叠系湖相烃源岩;车排子凸起东侧- 红车断裂带西侧新近系沙湾组油藏轻质原油来源于四棵树凹陷古近系湖相烃源岩;车排子凸起中部春光油田白垩系—古近系油藏稠油为二叠系来源稠油和侏罗系正常原油的混合原油,新近系沙湾组油藏稠油为二叠系来源稠油与新近系正常原油的混合原油;车排子凸起西部石炭系—古近系油藏轻质原油来源于四棵树凹陷中—下侏罗统煤系烃源岩,而新近系沙湾组油藏轻质原油来源于四棵树凹陷古近系湖相烃源岩。本文对准噶尔盆地西北缘南部地区油气藏成藏研究及区域油气勘探决策具有重要参考作用。  相似文献   

中新世黄河水系演化重建：来自钾长石Pb同位素的约束     

林旭  刘静  刘海金  胥勤勉  修方睿  李娜 《地质学报》2023,97(10):3438-3455

自剥蚀地貌中形成的剥蚀产物搬运到沉积区或汇水盆地沉积下来的过程,称为“源-汇”系统。从这些“汇”中识别“源”的信息,结合地层的沉积时代,约束黄河的形成时代、水系格局演化、流域内构造运动以及环境变迁成为黄河水系演化研究的重要内容。然而,时至今日学者们对黄河何时出现的认识并不一致,存在“中新世内流黄河和中新世外流黄河”之争。为了解决这些争议,我们运用大河物源示踪研究中新兴的碎屑钾长石Pb同位素方法,对黄河中下游沉积物开展碎屑钾长石Pb同位素分析(n=378),将其与长江中下游和华夏板块已报道的碎屑和基岩钾长石Pb同位素结果进行对比,结果表明三者之间的钾长石Pb同位素组成明显不同。台湾岛是中国东部陆架海中新世地层出露最齐全的地区。因而,我们将黄河中下游与台湾岛中新统的钾长石Pb同位素比值进行对比,结果表明二者之间不存在物源联系。结合中国东部渤海湾盆地、南黄海盆地和东海盆地中新统的物源示踪研究结果,说明黄河物质在中新世未流入上述盆地。总体而言,中国北方中新世的构造活动控制了黄河的演化过程,导致其此时处于分段演化阶段。  相似文献   

Latest Devonian to earliest Carboniferous conodont and carbon isotope stratigraphy of a shallow‐water sequence in South China     

Wenkun Qie  Xiang‐Dong Wang  Xionghua Zhang  Wenting Ji  Ethan L. Grossman  Xing Huang  Jiangsi Liu  Genming Luo 《Geological Journal》2016,51(6):915-935

To improve regional and intercontinental correlation of the uppermost Devonian–lowermost Carboniferous, we examined the conodont faunas and carbon isotopic records of the Tangbagou Formation in the Qilinzhai section, southern Guizhou, South China. The Tangbagou Formation is a succession of mixed carbonate–siliciclastic rocks that accumulated on a shallow‐water platform under normal marine conditions. Seven conodont zones for shallow‐water biofacies in South China, the Cl. gilwernensis–Cl. unicornis Zone, the Po. spicatus Zone, the Si. homosimplex Zone, the Si. sinensis Zone, the Si. eurylobata Zone, the Ps. multistriatus Zone and the Po. co. porcatus Zone in ascending order, are recognized in the Tangbagou Formation. Although apparently limited in its value for global correlation, this conodont zonation is more applicable to shallow‐water biofacies in South China. Carbonate samples have yielded carbon isotopic signatures consistent with those recorded in Euroamerica sections, in particular showing four distinct characteristics: (1) the peak values of Hangenberg Carbon Isotope Excursion (HICE) during the latest Devonian, (2) a minor positive shift (P1) in the Si. homosimplex Zone during the early Tournaisian, (3) a second minor positive shift (P2) in the Si. sinensis Zone and (4) the middle Tournaisian Carbon Isotope Excursion (TICE) in the middle part of the Tangbagou Formation. The similarity in peak values (~5.5‰) and magnitude of TICE for the Qilinzhai and Belgian sections indicates that the Euro‐asia δ¹³C_carb trends may reflect the changes in global mean ocean δ¹³C_DIC, rather than having been overprinted by local carbon cycling. Integration of conodont biostratigraphy and δ¹³C stratigraphy provides a powerful tool for stratigraphic correlation. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Helium and argon isotope geochemistry of natural gases in China’s petroliferous basins     

Wenhui Liu  Yongchang Xu  Mingxin Tao  Xiaobao Zhang 《中国地球化学学报》2011,30(1):19-32

The age-accumulation effect of 40Ar in hydrocarbon source rocks was discussed in accordance with the decay law of radioactive elements. In terms of the mean values of 40Ar/36Ar, the old Sinian gas reservoirs (mean values of 40Ar/36Ar: 7009) were definitely distinguished from the Permian gas reservoirs (mean values of 40Ar/36Ar: 1017) in Weiyuan, Sichuan Province, and the gas source of the Permian gas reservoir (mean values of 40Ar/36Ar: 5222) in well Wei-7 with the Weiyuan structure is defined as the Sinian system. Based on the values of 40Ar/36Ar, the coal-type gases (The source rocks are of the C-P system; mean values of 40Ar/36Ar: 1125) are definitely distinguished from the oil-type gases (The source rocks are of the Tertiary system; mean values of 40Ar/36Ar: 590) in the Tertiary reservoirs of the Zhongyuan Oilfield. Besides, 40Ar/36Ar values also have a positive effect on the oil-source correlation of oil reservoirs in ancient hidden mountains. According to the crust-mantle interchange information reflected by 3He/4He values, petroliferous provinces in China can be divided into three major tectonic regions. (1) The eastern active region: The crust-mantle volatile matter exchanges actively, and the 3He/4He values are mainly around 10-6, partly around 10-7. (2) The central stable region: The 3He/4He values are all around 10-8. (3) The western sub-stable region: The 3He/4He values are mainly around 10-8, and around 10-7 on the edges of the basins. Helium contents of some gas wells in China’s eastern petroliferous region reach the industrial abundance (He≈0.05%–0.1%), the 3He/4He values reach 10-6, and the equivalent values for the mantle-source components in helium gas can reach 30%–50%. As viewed from this, a new type of crust-mantle composite helium resources has been proposed. Geneses of some CO2 gas reservoirs in the east of China and some issues concerning mantle-source methane were discussed in the light of the helium and carbon isotopes of CO2 and CH4 in natural gases. In the discussion on helium isotopic characteristics of inclusions in the reservoirs, it was discovered that the 3He/4He values are close to those in natural gases. That is to say, this phenomenon is related to regional tectonism. The 3He/4He, CO2/3He and CH4/3He data were used to discuss the tectonic activities of fault zones in a certain number of regions in China.  相似文献   

广域电磁法深部找矿实验效果   总被引：1，自引：0，他引：1  

朱裕振  许聪悦 《物探与化探》2011,35(6):743-746

介绍了广域电磁法的基本原理、特点及广域视电阻率的定义。在内蒙古自治区某银铅锌矿进行了实验勘探工作,解释和推断了地电异常,并和可控源音频大地电磁法的效果进行了对比。研究结果表明:广域电磁法可以用较小的发收距获得较大的探测深度,勘探效率和精度较高,用于寻找深部金属矿的效果明显。  相似文献   

Zircon U-Pb ages and Hf isotopic characteristics of the Dehe biotite monzonitic gneiss pluton in the North Qinling orogen and their geological significance   总被引：1，自引：0，他引：1  

LEE Ben 《中国地球化学学报》2011,30(2):204-216

The Dehe granitic pluton intruded the Xiahe Group which is in the core complex of the North Qinling Orogenic Belt(NQOB).It shows gneissic bedding and possesses typical S-type granite minerals such as muscovite and garnet.LA-ICP-MS U-Pb isotopic dating of the Dehe granite yielded a weighted average age of 925±23 Ma which represents the emplacement age of the pluton.Most of the εHf(t) values are negative,and the two-stage model ages are consistent with the age of the Qinling Group.The isotope data show that the Dehe granite was formed in the following geological setting:in the syn-collision setting of the NQOB in the Neoproterozoic,crustal thickening induced partial melting of materials derived from the Qinling complex,and then the maga upwelled and intruded into the Xiahe Group.The formation of the Dehe S-type granite implied the occurrence of a convergent event in the QOB during the Neoproterozoic.  相似文献   

Geochemical Stratigraphy and Microvertebrate Assemblage Sequences across the Silurian/Devonian Transition in South China     

ZHAO Wenjin  WANG Nianzhong  ZHU Min  Ulrich MANN  Ulrich HERTEN  Andreas LüCKE 《《地质学报》英文版》2011,85(2):340-353

Carbon isotope (δ13Corg) analyses of non-marine clastic rocks and neritic carbonates and black shales spanning the Silurian/Devonian transition are compared from two richly fossiliferous sequences in Qujing of East Yunnan and Zoige of Sichuan, South China. The two sections, Xishancun and Putonggou sections in South China, reveal positive δ13Corg shifts happening in the Upper Pridoli and Lower Devonian and reaching peak values as heavy as ?25.2‰ (Xishancun) and ?19.9‰ (Putonggou) in the lowermost Lochkovian following the first occurrence of the thelodont Parathelodus and the conodont Icriodus woschmidti woschmidti (only in Putonggou Section and together with Protathyris-Lanceomyonia brachiopod fauna). These results replicate a globally known positive shift in δ13Corg from the uppermost Silurian to the lowermost Devonian. The δ13Corg variations across the Silurian/Devonian Boundary (SDB) at the two sections in South China exhibit a shift in carbon isotopic composition similar to the detailed SDB curves from the borehole Klonk-1 drilled at top of the Klonk Global Standard Stratotype-Section and Point (GSSP) in the Prague Basin, Czech Republic. In addition, four microvertebrate assemblages, including the Liaojiaoshan, Xishancun, Yanglugou and Xiaputonggou assemblages, are recognized from the Silurian/Devonian transition exposed in the Xishancun and Putonggou sections, respectively. The results from both carbon isotope stratigraphy and microvertebrate assemblage sequences suggest that the SDB in South China is located at the base of the Xishancun Formation (between sample QX-20 and sample QX-21) in the Xishancun Section and the lower part of the Xiaputonggou Formation (between sample ZP-09 and sample ZP-10) in the Putonggou Section. The isotopic trend for organic carbon together with the changes of microvertebrate remains across the SDB can offer an approach to a potential correlation of the SDB from different sedimentary facies, which help to correlate the marine with non-marine deposits.  相似文献   

The Impact of Aqueous Medium on Gas Yields and Kinetic Behaviors of Hydrogen Isotope Fractionation during Organic Matter Thermal Degradation     

LU Shuangfang  WANG Min  XUE Haitao  LI Jijun  CHEN Fangwen  XU Qingxia 《《地质学报》英文版》2011,85(6):1466-1477

In order to recognize the impact of aqueous medium on gas yields and the kinetic behaviors of hydrogen isotope fractionation during organic matter thermal degradation, the gold tube apparatus was used to conduct thermal simulation experiments by mixing the nC18 with the water of different properties and proportions. The yields of natural gas components, the relation among hydrogen isotope composition of each component and the experimental temperatures vs. heating rates have been obtained, and the results indicate that under the higher temperature conditions, the hydrous experiment has obvious impact on gas yields, such as when more water is added, higher amounts of hydrocarbon gas and H2 are yielded, and the existence of water obviously prolongs the temperature interval with the existence of heavy hydrocarbon gas. It also shows that the hydrogen isotope of hydrocarbon gas generated by the hydrous experiment is obviously lighter than that generated by the anhydrous experiment, and with the increasing amount of added water, the δD value of hydrocarbon gas gradually decreases. Compared with gas yields, the variation of δD value is more sensitive to aqueous medium in the thermal simulation experiment. However, compared with the amount of the added water, the aqueous medium property has smaller impact on the gas yields, which still shows the inherit effect on hydrogen isotope composition of aqueous medium. Through the model simulation and the isotope fractionation behavior analysis, it is validated that the hydrogen isotope fractionation process can be well described by the chemical kinetic model. The difference of reaction fraction of normal methane and D-containing methane is large, corresponding to the same activation energy. The content of normal methane is obviously higher in the part with lower activation energy, while the content of D-containing methane is higher in the part with higher activation energy. Therefore, it will result in larger hydrogen isotope fractionation amplitude, and the δD values will be more sensitive to the variation of maturity. Meanwhile, the average activation energy of methane generation from nC18 in the hydrous experiment is higher than that in the anhydrous experiment, and the greater amount of added water, the larger the average activation energy of methane generation reaction. This has laid foundation for its exploratory application in the study of gas reservoir forming history and the gas-source correlation, which indicates the research and application prospects in this orientation.  相似文献   

Sulfur Isotopes of Framboidal Pyrite in the Permian-Triassic Boundary Clay at Meishan Section     

ZHANG Jun  LIANG Handong  HE Xiaoqing  YANG Ye  CHEN Baohua 《《地质学报》英文版》2011,85(3):694-701

Pyrite framboids were found in the Permian-Triassic boundary at Meishan Section, while their sulfur isotopes were determined. The majority of framboids is less than 5 μm in diameter, with some large-sized framboids. Also, euhedral gypsums were observed in the boundary clay. The authors suppose that most of the pyrite framboids formed just below the redox boundary and stopped growing after entering the lower water column. The result indicates that it was probably lower dysoxia condition in the temporal ocean. Moreover, the authors also presume that some pyrite was oxidated to sulfates accompanying the fluctuation of redox condition, which would probably be the origin of the negative sulfur isotopes of gypsum and CAS reported before. In addition, sulfur isotope of framboidal pyrite suggests that sulfur is originated from bacterial sulfate reduction in anoxic condition. Therefore, this study confirms that the ocean was widely anoxic during the Permian-Triassic transitional period. However, the redox condition in temporal ocean was probably not stable, with short-term fluctuations.  相似文献   

Geochronology and Petrogenesis for the Protolith of Biotite Plagioclase Gneiss at Lianghe, Western Yunnan   总被引：5，自引：0，他引：5  

CONG Feng  LIN Shiliang  ZOU Guangfu  XIE Tao  LI Zaihui  TANG Fawei  PENG Zhimin 《《地质学报》英文版》2011,85(4):870-880

In this paper,we report an integrated study of U-Pb age and Hf isotope compositions of zircons from biotite plagioclase gneiss at Lianghe in western Yunnan.The zircons preserved inherited core and rim texture.Igneous zircon grains and rims yielded a weighted mean ~(206)Pb/~(238)U age of 120.4±1.7 Ma,theirε_(Hf)(120 Ma)values were mainly negative ranging from-13.9 to-10.7,with Hf model ages between 1.9 Ga and 2.0 Ga,some zircons had positiveε_(Hf)(120 Ma)values ranging from 0.2 to 2.1.The inherited cores ...  相似文献